Innovation is essential for long-term success in business and companies need to develop an innovative supply chain to respond to environmental and market challenges. It is necessary to develop knowledge through organizational learning in order to strengthen the ability of companies to innovate. An innovative supply chain is the basis for developing innovation in companies. To improve its market position companies should continuously receive high quality information from participants in the supply chain by sharing information. The complexity of relationships within supply chain affecting organizational learning is the subject of this study. We conducted an empirical study focusing our attention on agro-food companies in Bosnia and Herzegovina. A questionnaire was used as a data collection tool applying random systematic sampling and a total of 159 companies took part in this study. The empirical findings showed that sharing of information has a significant linkage with an innovative supply chain, but only in establishing partnerships with customers. We confirmed that an innovative supply chain is essential for development of organizational learning and agile supply chain. The findings could assist the managers of agro-food companies in Bosnia and Herzegovina to improve their business. This study provides guidance for improving business using supply chains.